Mobil Research and Development Corporation Field Research Laboratory Dallas, Texas

Abstract

The organic carbonaceous matter found intimately associated with the uranium mineral in some Crownpoint ore trends appears to shield some of the uranium from contact by a chemically-mild leaching system. Sodium hypochlorite (NaOCl) is an oxidant strong enough to attack this carbonaceous matter and contact the trapped uranium mineral. Batch and pack laboratory tests showed that alkaline bicarbonate solutions containing 0.1–5.0 wt-% NaOCl were effective for rapid recovery of uranium from Crownpoint refractory ore. Recoveries of 90% and greater were obtained In the laboratory tests. However, NaOCl is such a strong oxidant that it reacts extensively with gangue minerals also present in the ore as well as with uranium. Since oxidation with NaOCl generates sodium chloride, high chloride levels would tend to build up in the leaching circuit. Electron mlcroprobe studies of ore samples after leaching with NaOCl showed the presence of holes and cracks in the residual carbonaceous matrix as well as the presence of chloride. Leaching with NaOCl is also associated with high levels of dissolved organic carbon. These observations suggest some degree of oxidative breakdown of the encapsulating organic matter by NaOCl, thereby facilitating oxidant attack on the uranium mineral.

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