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Mercaptan
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Journal Articles
Journal:
Journal of Petroleum Technology
Publisher: Society of Petroleum Engineers (SPE)
J Pet Technol 64 (02): 28–32.
Paper Number: SPE-0212-0028-JPT
Published: 01 February 2012
...Kenneth Sheeran; Michael Murray; Jonathan Lehane; Tadg O'Flaherty Technology Update Tert-butyl mercaptan (TBM) and dimethyl sulfide (DMS) are odorous compounds added to natural gas to warn of a gas leakage so that an alarm can be activated. In a storage project for gas produced from platforms...
Journal Articles
Publisher: Society of Petroleum Engineers (SPE)
SPE Proj Fac & Const 6 (04): 166–172.
Paper Number: SPE-145501-PA
Published: 26 October 2011
...Renaud Cadours; Virenkumar Shah; Claire Weiss Summary Removing mercaptans from sour natural gas has always been considered a challenge. This is becoming an even more important issue with the global trend toward more-stringent specifications for commercial gases. Amines have been used extensively...
Proceedings Papers
Paper presented at the International Petroleum Technology Conference, December 7–9, 2009
Paper Number: IPTC-13362-MS
... Abstract Mercaptans are naturally occurring components of sour crude oil and natural gas condensate. When present in appreciable concentrations, they generate a very disagrenable smell which can be a nuisance to operators and to surrounding communities. Regulatory authorities aften require...
Proceedings Papers
Paper presented at the International Petroleum Technology Conference, December 7–9, 2009
Paper Number: IPTC-13512-MS
... Abstract Removing mercaptans from sour natural gas has always been considered as a challenge. This is becoming an even more important issue with the global trend towards more stringent specifications for commercial gases. Amines have been extensively used because of their ability to meet...
Proceedings Papers
Publisher: Society of Petroleum Engineers (SPE)
Paper presented at the Abu Dhabi International Petroleum Exhibition & Conference, November 13–16, 2017
Paper Number: SPE-188255-MS
...Introduction Abstract The formation of mercaptans and organosulfur species in Claus process leads to a reduction in the sulfur recovery efficiency, and an increase in the cost of tail gas treatment. While process optimization can be used to minimize their production in plants, the existing...
Proceedings Papers
Publisher: Society of Petroleum Engineers (SPE)
Paper presented at the SPE International Conference on Oilfield Chemistry, April 3–5, 2017
Paper Number: SPE-184589-MS
... Abstract Sulfur contaminants in the form of hydrogen sulfide and mercaptans are undesirable for various reasons during sour crude production. For example, hydrogen sulfide and mercaptans can be hazardous to personnel. Their presence can create major corrosion issues pertaining to the assets...
Proceedings Papers
Publisher: Society of Petroleum Engineers (SPE)
Paper presented at the SPE Middle East Oil & Gas Show and Conference, March 6–9, 2017
Paper Number: SPE-183974-MS
... Abstract Hydrogen sulfide and mercaptans are highly toxic. They can cause corrosion and contaminate fuels. For safe and efficient operation of oilfield applications, it is important to remove these constituents. Processes to remove sour gases with mercaptans include treatment of the hydrocarbon...
Proceedings Papers
Publisher: Society of Petroleum Engineers (SPE)
Paper presented at the Abu Dhabi International Petroleum Exhibition and Conference, November 9–12, 2015
Paper Number: SPE-177847-MS
... At the end of the nineties, production of new fields has resulted in an increase of the mercaptans content in sour gases sent to upstream plants of the GASCO complex. As a consequence, the mercaptan content of the NGL stream was significantly increased and Ruwais plant molecular sieves units have...
Proceedings Papers
Publisher: Society of Petroleum Engineers (SPE)
Paper presented at the SPE International Symposium on Oilfield Chemistry, April 11–13, 2011
Paper Number: SPE-141217-MS
... Abstract Mercaptans occur naturally in sour crude and condensate and cause an unpleasant odor which is a nuisance to operators and surrounding communities. Regulatory authorities often require control of mercaptan odors. A facility in Alberta stores condensate for use as a bitumen diluent...
Proceedings Papers
Publisher: NACE International
Paper presented at the CORROSION 2007, March 11–15, 2007
Paper Number: NACE-07565
... ABSTRACT Measured corrosion rates of carbon, low alloy, and stainless steels are significantly higher than that predicted by the modified McConomy curves in cases where significant concentrations of mercaptans are present in crude oils and hydrocarbon condensates. It suggested...
Proceedings Papers
Publisher: World Petroleum Congress
Paper presented at the 15th World Petroleum Congress, October 12–17, 1997
Paper Number: WPC-29271
... Abstract. A major increase in mercaptan-containing crudes and gas condensates makes crude demercaptanization (DMC) an extremely important problem. The light crudes and gas condensates of Tengiz, Janajolsk, Markovsk, Douglas, and Qatar condensates have a high mercaptan content as well...
Proceedings Papers
Publisher: Society of Petroleum Engineers (SPE)
Paper presented at the SPE Eastern Regional Meeting, October 23–25, 1996
Paper Number: SPE-37383-MS
... Abstract Mercaptans are added to odorless natural gas for safety reasons. In normal operations, gas companies add mercaptans to natural gas when delivered to the city gates station for commercial usage. Gas transported in gas transmission lines and underground gas storage fields normally does...
Journal Articles
Journal:
Corrosion
Publisher: NACE International
Corrosion 51 (07).
Paper Number: NACE-95070558
Published: 01 July 1995
...J. García-Antón; J. Monzó; J.L. Guiñón ABSTRACT INTRODUCTION Crude petroleum can contain a variety of sulfur compounds, such as elemental sulfur, mercaptans, sulfides, and disulfides.1-5 Most of these are removed during refining. Many of the sulfur compounds that remain in petroleum products...
Images
in A New Proprietary Hybrid-Solvent Process for Improved Mercaptan Removal
> SPE Projects, Facilities & Construction
Published: 26 October 2011
Fig. 1 Mercaptan removal on molecular sieves. More
Images
in A New Proprietary Hybrid-Solvent Process for Improved Mercaptan Removal
> SPE Projects, Facilities & Construction
Published: 26 October 2011
Fig. 2 Mercaptan removal in liquid C 3 /C 4 cuts. More
Images
in A New Proprietary Hybrid-Solvent Process for Improved Mercaptan Removal
> SPE Projects, Facilities & Construction
Published: 26 October 2011
Fig. 6 Mercaptan elimination vs. CO 2 +H 2 S removed from the raw gas. More
Images
Published: 09 November 2015
Figure 4 Mercaptan removal with molecular sieves More
Images
Published: 09 November 2015
Figure 5 Mercaptan removal with hybrid solvent More
Images
Published: 20 February 2012
Figure (5) Phase Equilibrium of Mercaptan in Extraction Section More
Images
Published: 11 November 2012
Figure 10 Treating line-up for sour gas with significant mercaptan concentration based on the conventional solvents (left scheme) and Sulfinol-X as acid gas removal solvent (right scheme). More
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