Polyelectrolyte-Complex Nanoparticles for Fluid-Loss Control in Oilwell Cementing
- Corbin D. Andersen (Texas A&M University) | Ying-Ying Lin (Texas A&M University) | Jenn-Tai Liang (Texas A&M University)
- Document ID
- Society of Petroleum Engineers
- SPE Drilling & Completion
- Publication Date
- June 2019
- Document Type
- Journal Paper
- 103 - 113
- 2019.Society of Petroleum Engineers
- carboxymethyl hydroxyethyl cellulose, polyethylenimine, fluid loss control, Polyelectrolyte complex, cementing
- 2 in the last 30 days
- 255 since 2007
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This paper focuses on the application of polyelectrolyte-complex (PEC) nanoparticles to fluid-loss control of oilwell cements. Cement-slurry design involves considerable complexities, including the interplay of viscosity, yield point (YP), fluid-loss control, setting time, sedimentation, gel-strength development, and density. Polymers such as hydroxyethyl cellulose (HEC), carboxymethyl HEC (CMHEC), and polyvinyl alcohol have been used extensively for fluid-loss control in oilwell cementing. However, the resulting increase in slurry viscosity often led to unwanted side effects, such as increased pumping requirements. PECs were originally developed as drug carriers for pharmaceutical applications. Our previous work (Cordova et al. 2008; Lin et al. 2014; Johnson et al. 2016) showed that they can also be effective in improved-oil-recovery applications. In this study, we explore the potential of using PEC nanoparticles to achieve effective fluid-loss control while maintaining good fluid properties of the cement slurry. Results from this proof-of-concept study demonstrated that a PEC system comprising common oilfield polymers can be used to achieve effective fluid-loss control. Simultaneously, the system shows improved rheological properties over control samples while maintaining other desirable slurry characteristics.
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Anandan, R., Johnson, S., and Barati, R. 2017. Polyelectrolyte Complex Stabilized CO2 Foam Systems for Hydraulic Fracturing Application. Presented at the SPE Liquids-Rich Basins Conference–North America, Midland, Texas, 13–14 September. SPE-187489-MS. https://doi.org/10.2118/187489-MS.
API RP10B-2, Recommended Practice for Testing Well Cements. 2013. Washington, DC: API.
API SPEC 10A, Specification for Cements and Materials for Well Cementing. 2010. Washington, DC: API.
Barati, R., Johnson, S. J., McCool, S. et al. 2011. Fracturing Fluid Cleanup by Controlled Release of Enzymes From Polyelectrolyte Complex Nanoparticles. J. Appl. Poplym. Sci. 121 (3): 1292–1298. https://doi.org/10.1002/app.33343.
Baret, J.-F., Leroy-Delage, S., and Dargaud, B. 2002. Cementing Compositions and Use of Such Compositions for Cementing Oil Wells or the Like. US Patent No. 20,040,007,360.
Berg, J. M. 2007. Biochemistry, sixth edition. New York City: W. H. Freeman.
Bijarbooneh, F. H., Zhao, Y., Kim, J. H. et al. 2013. Aqueous Colloidal Stability Evaluated by Zeta Potential Measurement and Resultant TiO2 for Superior Photovoltaic Performance. J. Am. Ceram. Soc. 96 (8): 2636–2643. https://doi.org/10.1111/jace.12371.
Bittleston, S. and Guillot, D. 1991. Mud Removal: Research Improves Traditional Cementing Guidelines. Oilfield Rev. 3 (2): 44–54.
Bose, C. C., Alshatti, B., Swartz, L. et al. 2014. Dual Application of Polyelectrolyte Complex Nanoparticles as Enzyme Breaker Carriers and Fluid Loss Additives for Fracturing Fluids. Presented at the SPE/CSUR Unconventional Resources Conference–Canada, Calgary, 30 September–2 October. SPE-171571-MS. https://doi.org/10.2118/171571-MS.
Buelichen, D. and Plank, J. 2011. Formation of Colloidal Polymer Associates From Hydroxyethyl Cellulose (HEC) and Their Role to Achieve Fluid Loss Control in Oil Well Cement. Presented at the SPE International Symposium on Oilfield Chemistry, The Woodlands, Texas, 11–13 April. SPE-141182-MS. https://doi.org/10.2118/141182-MS.
Bülichen, D. and Plank, J. 2012. Mechanistic Study on Carboxymethyl Hydroxyethyl Cellulose as Fluid Loss Control Additive in Oil Well Cement. J. Appl. Polym. Sci. 124 (3): 2340–2347. https://doi.org/10.1002/app.35278.
Cadix, A., Wilson, J., Barthet, C. et al. 2015. Diblock Copolymers: A New Class of Fluid Loss Control Additive for Oilfield Cementing. Presented at the SPE International Symposium on Oilfield Chemistry, The Woodlands, Texas, 13–15 April. SPE-173758-MS. https://doi.org/10.2118/173758-MS.
Cadix, A., Wilson, J., Phan, Ch. et al. 2016. New Diblock Copolymers as Fluid Loss Additive for High Temperature Cementing. Presented at the SPE Annual Technical Conference and Exhibition, Dubai, 26–28 September. SPE-181272-MS. https://doi.org/10.2118/181272-MS.
Chatterji, J. and Borchardt, J. K. 1981. Applications of Water-Soluble Polymers in the Oil Field. J Pet Technol 33 (11): 2042–2056. SPE-9288-PA. https://doi.org/10.2118/9288-PA.
Chatterji, J., Brenneis, D. C., and Hundt, G. R. 2014. Encapsulated Fluid-Loss Additives for Cement Compositions. US Patent No. 20,160,017,688.
Clark, P. E., Sundaram, L., and Balakrishnan, M. 1990. Yield Points in Oilfield Cement Slurries. Presented at the SPE Eastern Regional Meeting, Columbus, Ohio, 31 October–2 November. SPE-21279-MS. https://doi.org/10.2118/21279-MS.
Cordova, M., Cheng, M., Trejo, J. et al. 2008. Delayed HPAM Gelation via Transient Sequestration of Chromium in Polyelectrolyte Complex Nanoparticles. Macromolecules 41 (12): 4398–4404. https://doi.org/10.1021/ma800211d.
Crema, S. C., Kucera, C. H., and Konrad, G. 1989. New Fluid-Loss Additives for Oilfield Cementing. Presented at the SPE Production Operations Symposium, Oklahoma City, 13–14 March. SPE-18901-MS. https://doi.org/10.2118/18901-MS.
Davies, R. J., Almond, S., Ward, R. S. et al. 2014. Oil and Gas Wells and Their Integrity: Implications for Shale and Unconventional Resource Exploitation. Mar. Petrol. Gel. 56 (September): 239–254. https://doi.org/10.1016/j.marpetgeo.2014.03.001.
Desbrieres, J. 1993. Cement Cake Properties in Static Filtration: Influence of Polymeric Additives on Cement Filter Cake Permeability. Cement Concrete Res. 23 (2): 347–358. https://doi.org/10.1016/0008-8846(93)90100-N.
Devereux, S. 1998. Practical Well Planning and Drilling Manual. Tulsa: PennWell Books.
Dugonjic-Bilic, F. and Plank, J. 2011. Polyelectrolyte Complexes From Polyethylene Imine/Acetone Formaldehyde Sulfite Polycondensates: A Novel Reagent for Effective Fluid Loss Control of Oil Well Cement Slurries. J. Appl. Polym. Sci. 121 (3): 1262–1275. https://doi.org/10.1002/app.33228.
Foroushan, H. K., Ozbayoglu, E. M., Miska, S. Z. et al. 2018. On the Instability of the Cement/Fluid Interface and Fluid Mixing. SPE Drill & Compl 33 (1): 63–76. SPE-180322-PA. https://doi.org/10.2118/180322-PA.
Gandelman, R., Miranda, C., Teixeira, K. et al. 2004. On the Rheological Parameters Governing Oilwell Cement Slurry Stability. Ann. Trans. Nordic Rheol. Soc. 12: 85–91.
Greaves, C. and Hibbert, A. 1990. Test Improves Measurement of Cement-Slurry Stability. Oil Gas J. 88 (7).
Gubbala, S. 2012. Polyelectrolyte Complex: A Pharmaceutical Review. Int. J. Pharm. Biol. Sci. 2 (3): 399–407.
Ho, J. F., Tavassoli, S., Patterson, J. W. et al. 2016. The Use of a pH-Triggered Polymer Gelant to Seal Cement Fractures in Wells. SPE Drill & Compl 31 (3): 225–235. SPE-174940-PA. https://doi.org/10.2118/174940-PA.
Jackson, R. B. 2014. The Integrity of Oil and Gas Wells. Proc. Natl. Acad. Sci. 111 (30): 10902–10903. https://doi.org/10.1073/pnas.1410786111.
Johnson, S., Berkland, C., Moradi-Araghi, A. et al. 2016. Low Molecular Weight Polyacrylates for EOR. US Patent No. 20,160,115,371.
Lin, Y. Y., Berkland, C., Liang, J. T. et al. 2014. Delayed Gelling Agents. US Patent No. 20,140,209,305.
Lu, H., Xie, C., Gao, Y. et al. 2016. Cement Slurries With Rheological Properties Unaffected by Temperature. SPE Drill & Compl 30 (4): 316–321. SPE-178922-PA. https://doi.org/10.2118/178922-PA.
Mai, C.-T., Kadri, E.-H., Ngo, T.-T. et al. 2014. Estimation of the Pumping Pressure From Concrete Composition Based on the Identified Tribological Parameters. Adv. Mater. Sci. Eng. 2014: 503850. https://doi.org/10.1155/2014/503850.
McKenzie, L. F. and McElfresh, P. M. 1982. Acrylamide/Acrylic Acid Copolymers for Cement Fluid Loss Control. Presented at the SPE Oilfield and Geothermal Chemistry Symposium, Dallas, 25–27 January. SPE-10623-MS. https://doi.org/10.2118/10623-MS.
Mueller, D. T. 1992. Performance Characteristics of Vinylsulfonate-Based Cement Fluid-Loss Additives. Presented at the SPE Rocky Mountain Regional Meeting, Casper, Wyoming, 18–21 May. SPE-24380-MS. https://doi.org/10.2118/24380-MS.
Nelson, E. B. 2009. Well Cementing. Houston: Schlumberger Educational Services.
Pelipenko, S. and Frigaard, I. 2004. Mud Removal and Cement Placement During Primary Cementing of an Oil Well–Part 2; Steady-State Displacements. J. Eng. Math. 48 (1): 1–26. https://doi.org/10.1023/B:ENGI.0000009499.63859.f0.
Plank, J., Lummer, N. R., Dugonjic´-Bilic´, F. et al. 2009a. Comparative Study of the Working Mechanisms of Different Cement Fluid Loss Polymers. Presented at the SPE International Symposium on Oilfield Chemistry, The Woodlands, Texas, 20–22 April. SPE-121542-MS. https://doi.org/10.2118/121542-MS.
Plank, J., Lummer, N. R., and Dugonjic-Bilic, F. 2009b. Physico-Chemical Interactions Perturbing the Effectiveness of an ATBS-Based Fluid Loss Polymer Used in Oil Well Cementing. Presented at the SPE International Symposium on Oilfield Chemistry, The Woodlands, Texas, 20–22 April. SPE-121541-MS. https://doi.org/10.2118/121541-MS.
Plank, J., Tiemeyer, C., Bu¨ lichen, D. et al. 2013. A Review of Synergistic and Antagonistic Effects Between Oilwell Cement Additives. Presented at the SPE International Symposium on Oilfield Chemistry, The Woodlands, Texas, 8–10 April. SPE-164103-MS. https://doi.org/10.2118/164103-MS.
Rogers, M. J., Dillenbeck, R. L., and Eid, R. N. 2004. Transition Time of Cement Slurries, Definitions and Misconceptions, Related to Annular Fluid Migration. Presented at the SPE Annual Technical Conference and Exhibition, Houston, 26–29 September. SPE-90829-MS. https://doi.org/10.2118/90829-MS.
Roshan, H. and Asef, M. R. 2010. Characteristics of Oil Well Cement Slurry Using CMC. SPE Drill & Compl 25 (3): 328–335. SPE-114246-PA. https://doi.org/10.2118/114246-PA.
Salehi, R. and Paiaman, A. M. 2009. A Novel Cement Slurry Design Applicable to Horizontal Well Conditions. Petrol. Coal. 51 (4): 270–276.
Stout, C. M. and Wahl, W. W. 1960. A New Organic Fluid-Loss-Control Additive for Oilwell Cements. J Pet Technol 12 (9): 20–24. SPE-1455-G. https://doi.org/10.2118/1455-G.
Strange, A. F. and Brothers, L. E. 1990. Synthetic Polymer Developed for Cement Fluid-Loss Control. Presented at the SPE California Regional Meeting, Ventura, California, 4–6 April. SPE-20043-MS. https://doi.org/10.2118/20043-MS.
Veisi, M., Johnson, S., Peltier, K. et al. 2018. Application of Polyelectrolyte Complex Nanoparticles to Increase the Lifetime of Poly Vinyl Sulfonate Scale Inhibitor. Presented at the SPE International Conference and Exhibition on Formation Damage Control, Lafayette, Louisiana, 7–9 February. SPE-189564-MS. https://doi.org/10.2118/189564-MS.
Vignes, B. 2011. Contribution to Well Integrity and Increased Focus on Well Barriers From a Life Cycle Aspect. PhD dissertation, University of Stavanger, Stavanger, Norway (August 2011).
Zimmermann, R., Norde, W., Stuart, M. A. C. et al. 2005. Electrokinetic Characterization of Poly(acrylic Acid) and Poly(ethylene Oxide) Brushes in Aqueous Electrolyte Solutions. Langmuir 21 (11): 5108–5114. https://doi.org/10.1021/la050191p.