Abstract

The effectiveness of poly (2-acrylamido-2-methylpropane sulfonic acid) (PAMPS) and copolymers with acrylic acid (AA) and acrylamide (AM) magnetic nanogels as protective corrosion of CS in reaction with water by (EIS), (EFM) and tafel polarization method. Polarization method demonstrated that all the polymers are mixed inhibitor type. (EIS) Electrochemical impedance given that the attendance of these investigated polymers declines the double layer capacitance and improvement the charge transfer resistance. The polymers adsorption on surface of steel was follow isotherm Temkin. The morphology of the CS surface was examining by (EDX) energy dispersive X-ray and (SEM) scanning electron microscope. The data obtain showed improvement in efficiencies for inhibition with raising the dose of inhibitor.

Introduction

CS is the common regularly utilized pipeline materials as a part of petroleum creation. In any case, it is exceptionally inclined to corrosion in environments include sulphur [1]. Corrosion of sulfur has been one of the corrosion sorts in gas/oil manufacture, offering ascend to the pipelines failure and equipment's and utilized in biggest economic reduction and accidents. Likewise, spillage of raw petroleum because of endures consumption of pipelines would actuate fire accident, and natural contamination [2-4]. Explored to comprehend its mechanism, decrease the corrosion rate, additionally create experimental models to survey and foresee the parametric effects and the states-of the-art of internal corrosion of pipelines [5-12]. Theoretical approaches provide means of experimental of these reactions and there are many reports connection with this area [13]. Last papers have study the connection between the efficiency and structure of the inhibitor molecule, but low attention has been paid to the reliance of the protection efficiency on the size and electronic distribution of the protective molecule, Relation between chemical structure and inhibition efficiency was not research, The super paramagnetic Fe3O4 nanoparticles covered with polymers are usually connected to the magnetic cores to ensure a strong magnetic [14]. Attractive nanogels of regular interest are ferromagnetic magnetite (Fe3O4) covered with cross-connected polymer nanogels. The Fe3O4 center has solid attractive characteristic and super paramagnetic conduct, is of generally declines danger to the human body when epitomized in the defensive shell of polymer, which is cross-connected hydrogels polymer. The shell keeps the Fe3O4 center from total oxidation. In this appreciation, the utilizing of nanogels particles as a part of the field of consumption hindrance insurance for steel rather than ordinary natural inhibitors can deliver uniform flimsy film (with no pine opening because of cross-connected polymers) on the surface of CS to coat all surface with no deformities which give focal points over typical natural inhibitors. A few strategies have been produced to get ready attractive miniaturized scale and nanogels, for example, reverse microemulsion polymerization and emulsion polymerization [15-18]. The target of this paper is to calculation the inhibitive effect of these polymers on carbon steel in formation water by various electrochemical methods.

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