Abstract

Monoethanolamine (MEA) hydrochloride salts, which are formed from the use of hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triazine (commonly referred to as MEA triazine), a hydrogen sulfide scavenger, can create major corrosion issues inside an atmospheric crude oil distillation unit. Recently, deposit formation has been observed in a crude unit processing significant quantities of tight oil; these deposits result from polymerization of dithiazines (a reaction byproduct of MEA triazine) in the presence of hydrogen sulfide. Such fouling has been reported in upstream applications. This paper highlights the effects of such fouling occurring in downstream refining.

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