Abstract
For pipelines running across cold regions; soil temperature at the depth of buried pipeline would be sub-zero. However, whether the -0.85VCSE protection potential criteria or a more positive one was applicable for this situation was still an issue. In this paper, the electrochemical behavior of X80 steel in sub-zero NS4 solutions (a usually used soil simulation solution with 0.483g/L NaHCO3, 0.122g/L KCl, 0.181 g/L CaCl2·2H2O, 0.131g/L MgSO4·2H2O) at different temperature (with ethylene glycol added to avoid freezing) was studied by EIS and polarization curve using a Pt wire as reference electrode. The results showed that with the temperature decreasing, the polarization resistance increased and the corrosion current decreased, which was the same as the common experience. A polarization potential less negative than -0.85VCSE in the sub-zero experimental environment would be adequate to reduce the general corrosion rate to less than 0.025mm/yr as required in NACE standard and 0.01mm/yr as required in ISO standard.