Abstract

Geological carbon sequestration represents a long-term storage of CO2, in which large-scale CO2 is injected into the subsurface geologic formations, such as the deep saline aquifers or depleted oil and gas reservoir. In the CO2 sequestration process, the injected CO2 is expected to remain in the reservoir and not to migrate to the earth surface. To better understand the CO2 movement undersurface and obtain real time information in carbon sequestration, an iridium oxide-based Severinghaus-type CO2 chemical sensor was constructed and tested in this study.

The CO2 sensor was designed and constructed based on the intersection inspiration from electrochemistry idea. The principle of the CO2 sensor design is dramatically rely on the pH detection of the electrolyte solution which generated by the hydrolysis process of CO2. The developed CO2 sensor includes a couple of Iridium-Oxide electrodes. To meet the working purpose, iridium oxide nanoparticles was prepared and electrodeposited for the thin IrO2 film generation on the surface of metal substrate. The other critical parts, such as a thin gas-permeable silicone membrane, a porous metal supporting material, and the bicarbonate-based electrolyte solution are prepared for the sensor's preparation. The assembled sensor was tested in aqueous solution with different CO2 concentrations. Then the sensor was settled in harsh, high-pressure environments, in order to invest the performance of the CO2 sensor under reservoir conditions.

Introduction

The definition of CO2 sequestration was the whole process of the CO2 capture and the CO2 long-term storage [1]. It had been treated as a potential method to decelerate the accumulation process of greenhouse gas which generated from the fossil fuels burning and other source [2]. While for the geologic sequestration, it means to put the captured CO2 in the geological formation for the aim of long-term storage.

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